We document an example of serpentinization of olivine and orthopyroxene that produced virtually no magnetite, but instead relatively Fe-rich yellow-colored lizardite (XFe = 0.08 to 0.17), and the native Fe-Ni-Co metals, awaruite and wairauite. Lizardite's identity was confirmed by micro-Raman spectroscopy, although peaks are broad. Electron microprobe analyses of the lizardite yield a continuous compositional trend of formula contents suggestive of the progressive uptake Of Fe3+ exclusively on M sites, where it is charge balanced by vacancies. Although these observations are unusual, this secondary mineral assemblage can be explained in terms of the likely intensive variables T, fH2O,fH2, d aSiO2 attending the alteration. The absence of magnetite in serpentinization does not signify a lack of oxidation. By forming the hydrated phase-component ferri-lizardite instead of magnetite from the fayalite and ferrosilite components, the yield of hydrogen is reduced by two-thirds. The usual inverse correlation of rock density with magnetic susceptibility is unlikely to be the case in this kind of serpentinization.
CITATION STYLE
Evans, B. W., Kuehner, S. M., & Chopelas, A. (2009). Magnetite-free, yellow lizardite serpentinization of olivine websterite, Canyon Mountain complex, N.E. Oregon. American Mineralogist, 94(11–12), 1731–1734. https://doi.org/10.2138/am.2009.3301
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