A microporous lanthanide-organic framework

  • Reineke T
  • Eddaoudi M
  • O'Keeffe M
 et al. 
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Abstract

Stable zeolite-like microporosity, even in the absence of guest molecules, is exhibited by a lanthanide-benzenedicarboxylate (BDC) framework, which was synthesized by the copolymerization of Tb(III) and 1,4-benzenedicarboxylic acid. The open Tb-BDC framework adopts an expanded PtS network structure (see diagram; Tb: open circles; C: full circles; lines connecting Tb to C represent O atoms, and those connecting C atoms are benzene rings) and is capable of reversible gas and liquid sorption.

Author-supplied keywords

  • Host-guest chemistry
  • Lanthanides
  • Microporosity
  • Zeolite anlogues

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Authors

  • Theresa M. Reineke

  • Mohamed Eddaoudi

  • M. O'Keeffe

  • Omar M. Yaghi

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