Nature of polarized excitons

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Abstract

The problem of calculating optical absorption spectra in molecular aggregates was revisited using a Hamiltonian for the molecular aggregate. The polarized exciton was found to be identical in its form to the classical dipole equation. As a result, the exact microscopic definitions of the entities of occurring in the classical dipole theory was obtained.

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Ambjörnsson, T., & Apell, S. P. (2001). Nature of polarized excitons. Journal of Chemical Physics, 114(8), 3365–3372. https://doi.org/10.1063/1.1343873

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