Well dispersed Pd nanoparticles supported on amino functionalized
metal-organic frameworks MIL-53(Al)-NH(2) (Al(OH)[H(2)N-BDC], H(2)N-BDC=2-aminoterephthalic
acid, MIL=Materials of Institut Lavoisier) were prepared using a
direct anionic exchange approach and subsequent reduction with NaBH(4).
The Pd/MIL-53 (Al)-NH(2) catalyst exhibitted high activity and good
stability for Suzuki-Miyaura cross-coupling reaction. (C) 2011 Elsevier
B.V. All rights reserved.
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