Well dispersed Pd nanoparticles supported on amino functionalized metal-organic frameworks MIL-53(Al)-NH2(Al(OH)[H2N-BDC], H2N-BDC = 2-aminoterephthalic acid, MIL = Materials of Institut Lavoisier) were prepared using a direct anionic exchange approach and subsequent reduction with NaBH4. The Pd/MIL-53(Al)-NH2catalyst exhibitted high activity and good stability for Suzuki-Miyaura cross-coupling reaction. © 2011 Elsevier B.V. All rights reserved.
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