Photochemistry of tetracene adsorbed on dry silica: Products and mechanism

  • Dabestani R
  • Nelson M
  • Sigman M
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Abstract

The photochemistry of tetracene (1) has been studied on dry silica at very low surface coverages (less than 3% of a monolayer). Irradiation of degassed samples of 1 adsorbed on silica surface proceeds very slowly to produce both syn (2) and anti (3) dimers. Under aerated conditions photolysis of 1 at surface coverages of

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