Pillared covalent organic frameworks with balanced volumetric and gravimetric hydrogen uptake

  • Kim D
  • Jung D
  • Kim K
 et al. 
  • 39


    Mendeley users who have this article in their library.
  • 12


    Citations of this article.


On the basis of our modeling of pillared covalent organic frameworks (PCOFs) with pyridine molecules inserted between the COF-1 layers, we propose that the surface area and free volume of storage materials should be balanced to increase the gravimetric and volumetric hydrogen uptake capacities. Density functional theory and grand canonical Monte Carlo simulations show that these PCOFs have significantly improved gravimetric and volumetric hydrogen storage capacities of 8.8-10.0 wt % and 58.7-61.7 g L-1, respectively.

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document


Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free