Polycondensation of dibromofluorene analogues with tetrafluorobenzene via direct arylation

  • Lu W
  • Kuwabara J
  • Kanbara T
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Abstract

The polycondensation of 1,2,4,5-tetrafluorobenzene with 2,7-dibromo-9,9-dioctylfluorene or 3,6-dibromo-N-octadecylcarbazole via direct arylation was carried out under various conditions. Owing to their high mol. wt., free-standing films of PDOF-TP and POC-TP can be fabricated by a soln.-casting method. The films and the soln. of the polymers exhibited blue fluorescence in soln. and film states. [on SciFinder(R)]

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