Nitric oxide binds reversibly to the Fe(III) complex of a well-developed tetra-amido macrocyclic ligand. Reaction with NO results in formation of a species consistent with an S= 1 (Fe–NO)6 ground state as characterized by UV-vis, IR, EPR, and Mössbauer spectroscopy. The resultant nitrosyl is labile and dissociates readily upon purging with N2, thus providing a rare example of reversible NO binding to non-heme iron. © 2012 The Royal Society of Chemistry.
CITATION STYLE
Pluth, M. D., & Lippard, S. J. (2012). Reversible binding of nitric oxide to an Fe(III) complex of a tetra-amido macrocycle. Chemical Communications, 48(98), 11981–11983. https://doi.org/10.1039/c2cc37221e
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