Hydrogenation of a benzene ruthenium chloride dimer in the presence of novel acylphosphine (phosphomide) ligands resulted in the formation of corresponding ruthenium(II)-benzyl phosphine complexes. Here, selective reduction of the carbonyl group to a methylene unit takes place with molecular hydrogen under mild conditions in good yield. This approach provides an alternative synthesis of ruthenium phosphine complexes of benzyl and heterobenzyl phosphine ligands. © 2013 American Chemical Society.
CITATION STYLE
Gowrisankar, S., Neumann, H., Spannenberg, A., & Beller, M. (2014). Selective hydrogenation of ruthenium acylphosphine complexes. Organometallics, 33(1), 94–99. https://doi.org/10.1021/om4008086
Mendeley helps you to discover research relevant for your work.