A time-resolved infrared-ultraviolet double-resonance technique is used to characterize specific rovibrational states pumped by a pulsed CO(2) laser within the nu(4) vibrational ladder of D(2)CO. The roles of rotational and quasiresonant rovibrational relaxation, requiring, respectively, < or =1 and approximately 3 gas-kinetic collisions, are studied. The rotational specificity of the latter suggests that a collision-assisted sequence of infrared absorption steps is able to account for the selective initial stages of multiple-photon excitation in formaldehyde.
CITATION STYLE
Orr, B. J., & Haub, J. G. (1981). Selective infrared excitation in D_2CO: rotational assignments and the role of collisions. Optics Letters, 6(5), 236. https://doi.org/10.1364/ol.6.000236
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