Selective Solid State Photooxidant

  • Morkin T
  • Turro N
  • Kleinman M
 et al. 
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Irradiation of biphenyl encapsulated in the cavities of a NaZSM-5 zeolite framework has been reported to result in the formation of an extremely long-lived radical cation. Here, we show that such zeolite encapsulated radical cations can act as irreversible one-electron oxidants for simple alkenes and dienes, in a solid-state analogue to solution-phase cosensitization. Compared to the well-known semiconductor photooxidizers, such as titanium dioxide, the NaZSM-5 zeolite-based solid photooxidants exhibit enhanced selectivity based on oxidation potential, molecular size and shape, and Lewis base character.

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  • Tracy L. Morkin

  • Nicholas J. Turro

  • Mark H. Kleinman

  • Cheyenne S. Brindle

  • Wolfgang H. Kramer

  • Ian R. Gould

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