Stable Multiresponsive Luminescent MOF for Colorimetric Detection of Small Molecules in Selective and Reversible Manner

  • Khatua S
  • Goswami S
  • Biswas S
 et al. 
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Abstract

A novel Cu(I)-based two-dimensional (2D, 4 4 net) metal−organic framework (MOF) [Cu(L)(I)] 2n ·2nDMF· nMeCN (1); L = 4′-(4-methoxyphenyl)-4,2′:6′,4″-terpyridine; DMF = N,N-dimethylformamide, MeCN = acetonitrile) has been synthesized and found to behave as a colorimetric detector for the widest variety of small molecules such as different solvents, halobenzenes, N-heterocycles, amine, and nitroaromatic explosives all in vapor phase through a single crystal to single crystal (SCSC) transformation. The 2D 4 4

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