The state of metallic phase in alumina-supported platinum-chromium catalysts

  • Engels S
  • Lausch H
  • Peplinski B
 et al. 
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Abstract

The reduction behaviour and the phase composition of platinum-chromium samples (unsupported and on alumina carrier) were investigated with the help of temperature-programmed reduction (TPR), X-ray diffraction, ferromagnetic resonance (FMR) spectroscopy and ethane hydrogenolysis. Co-reduction and the formation of alloys was found to occur when H2PtCl6and (CrO3)xwere used as starting materials. Annealing of the samples above 500°C led to the formation of a ferromagnetic Pt3Cr superlattice. Addition of chromium to platinum/alumina attenuates the hydrogenolysis activity; annealing results in an additional strong decrease of this demanding reaction. © 1989.

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Authors

  • Siegfried Engels

  • Hartmut Lausch

  • Burkhard Peplinski

  • Michael Wilde

  • Wolfgang Mörke

  • Peter Kraak

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