We develop a lattice model for the splay flexoelectric effect in nematic liquid crystals. In this model, each lattice site has a spin representing the local molecular orientation, and the interaction between neighboring spins represents pear-shaped molecules with shape polarity. We perform Monte Carlo simulations and mean-field calculations to find the behavior as a function of interaction parameters, temperature, and applied electric field. The resulting phase diagram has three phases: isotropic, nematic, and polar. In the nematic phase, there is a large splay flexoelectric effect, which diverges as the system approaches the transition to the polar phase. These results show that flexoelectricity can be a statistical phenomenon associated with the onset of polar order. © 2010 The American Physical Society.
CITATION STYLE
Dhakal, S., & Selinger, J. V. (2010). Statistical mechanics of splay flexoelectricity in nematic liquid crystals. Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, 81(3). https://doi.org/10.1103/PhysRevE.81.031704
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