The structural characteristics of novel alkaline-earth suborthosilicate glasses along the compositional join (1 - x)(Ca0.5Mg0.5O) - xSiO2 with 0.28 ≥ x ≥ 0.33 are investigated using high resolution 29Si and 17O nuclear magnetic resonance spectroscopy. The structures of these glasses consist of isolated Q0 and Q1 anionic species and Mg2+ and Ca2+ countercations that are held together by Coulombic interactions. The concentration of the Q1 species rapidly decreases with decreasing SiO2 content and becomes undetectable in the glass with x = 28 mol %. The compositional variation of the physical properties of these glasses such as glass transition temperature and density can be attributed to the Q-speciation in the structure. The NBOs are associated with a random distribution of the alkaline-earth cations in their nearest neighbor coordination shell. The resulting random packing of dissimilar Ca-NBO and Mg-NBO coordination polyhedra may give rise to structural and topological frustration responsible for the unusual glass-forming ability of these suborthosilicate liquids with extremely low SiO2 contents. Finally, the composition and the formation of Q1 species necessitate the formation of free O2- ions in the structure of these glasses that are only bonded to Mg2+ and Ca2+ cations. The 17O NMR results presented in this study allow for direct observation of such oxygen species. © 2012 American Chemical Society.
CITATION STYLE
Nasikas, N. K., Edwards, T. G., Sen, S., & Papatheodorou, G. N. (2012). Structural characteristics of novel Ca-Mg orthosilicate and suborthosilicate glasses: Results from 29Si and 17O NMR spectroscopy. Journal of Physical Chemistry B, 116(9), 2696–2702. https://doi.org/10.1021/jp212469p
Mendeley helps you to discover research relevant for your work.