Abstract
The azine bridged dicatechol ligand (E,E)-benzaldehyde azine (H4L) was fully characterized by X-ray analysis. The reaction of [ReCl6]2- with this compound was studied and the novel Re(IV) complex (HNEt3)(NBu4)[ReCl4(H2L)] was prepared and characterized. The structure and spectroscopy of the compound H4L and its Re(IV) complex were studied experimentally and by means of density functional calculations. © 2009 Elsevier B.V. All rights reserved.
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Pintos, V., Cuevas, A., Onetto, S., Seoane, G., Denis, P. A., Gancheff, J. S., … Kremer, C. (2010). Structural and theoretical studies of (E,E)-benzaldehyde azine and its rhenium(IV) complex. Journal of Molecular Structure, 963(1), 9–15. https://doi.org/10.1016/j.molstruc.2009.09.028
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