Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(ii) bis(trimethylsilyl)amide

  • Layfield R
  • McDouall J
  • Scheer M
 et al. 
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Abstract

The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC complexes [(NHC)Fe{N(SiMe3)2}2] (NHC = IPr, 2; NHC = IMes, 3) are reported.

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Authors

  • Joseph McDouallUniversity of Manchester

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  • Richard A. Layfield

  • Manfred Scheer

  • Christoph Schwarzmaier

  • Floriana Tuna

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