Skip to content
Journal article

Subpicosecond intersystem crossing in mono- and Di(organophosphine)gold(I) naphthalene derivatives in solution

Vogt R, Gray T, Crespo-Hernández C ...see all

Journal of the American Chemical Society, vol. 134, issue 36 (2012) pp. 14808-14817

  • 31

    Readers

    Mendeley users who have this article in their library.
  • 29

    Citations

    Citations of this article.
  • N/A

    Views

    ScienceDirect users who have downloaded this article.
Sign in to save reference

Abstract

Femtosecond-to-microsecond broadband transient absorption experiments are reported for Cy(3)PAu(2-naphthyl) (1), (Cy(3)PAu)(2)(2,6-naphthalenediyl) (2), and (Cy(3)PAu)(2)(2,7-naphthalenediyl) (3), where Cy = cyclohexyl. Global and target analyses of the data, based on a sequential kinetic model, reveal four spectral components. These components are assigned to (1) excited state absorption (ESA) of the ligand-centered S(1) state; (2) ESA of a receiver ligand-to-metal or metal-to-ligand charge transfer triplet state (tau(1)

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document

Get full text

Authors

Cite this document

Choose a citation style from the tabs below