Subpicosecond intersystem crossing in mono- and Di(organophosphine)gold(I) naphthalene derivatives in solution

  • Vogt R
  • Gray T
  • Crespo-Hernández C
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Femtosecond-to-microsecond broadband transient absorption experiments are reported for Cy(3)PAu(2-naphthyl) (1), (Cy(3)PAu)(2)(2,6-naphthalenediyl) (2), and (Cy(3)PAu)(2)(2,7-naphthalenediyl) (3), where Cy = cyclohexyl. Global and target analyses of the data, based on a sequential kinetic model, reveal four spectral components. These components are assigned to (1) excited state absorption (ESA) of the ligand-centered S(1) state; (2) ESA of a receiver ligand-to-metal or metal-to-ligand charge transfer triplet state (tau(1)

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