Synthesis and characterization of all-conjugated copolymers of 3-hexyl-thiophene and EDOT by grignard metathesis polymerization

  • Miozzo L
  • Battaglini N
  • Braga D
 et al. 
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Abstract

Random regioregular copolymers of 3-hexylthiophene and 3,4-ethylenedioxythiophene were synthesized by grignard metathesis polymerization. Soluble copolymers were obtained with a high degree of regioregularity and with a monomer ratio close to the feed ratio. A comparison between the optical properties and the thin film morphologies of these copolymers and poly(3-hexylthiophene) is also presented. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011

Author-supplied keywords

  • P3HT
  • PEDOT
  • conducting polymers
  • conjugated polymers; GRIM polymerization
  • copolymerization

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Authors

  • Luciano Miozzo

  • Nicolas Battaglini

  • Daniele Braga

  • Loïg Kergoat

  • Clément Suspène

  • Abderrahim Yassar

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