Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex

  • Bejger C
  • Tian Y
  • Barker B
 et al. 
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Abstract

A new tetrathiafulvalene-salphen uranyl complex has been prepared. The system was designed to study the electronic coupling between actinides and a redox active ligand framework. Theoretical and experimental methods--including DFT calculations, single crystal X-ray analysis, cyclic voltammetry, NMR and IR spectroscopies--were used to characterize this new uranyl complex.

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Authors

  • Christopher Bejger

  • Yong Hui Tian

  • Beau J. Barker

  • Kevin S. Boland

  • Brian L. Scott

  • Enrique R. Batista

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