Synthesis of spiro-bisperoxyketals

  • Ghorai P
  • Dussault P
  • Hu C
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Syntheses of spirocyclic bis-1,2-dioxolanes, bis-1,2-dioxanes, and bis-1,2-dioxepanes are achieved through intramolecular ketalizations of hydroperoxy ketones or intramolecular alkylations of gem-dihydroperoxides. The spiroperoxides have excellent thermal and chemical stability, and several display promising activity against P. falciparum.

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  • Prasanta Ghorai

  • Patrick H. Dussault

  • Chunhua Hu

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