Synthesis of tetrafluoroethyl- and tetrafluoroethylene-containing amines by the reaction of silanes with enamines under acidic conditions

  • Chernykh Y
  • Jurásek B
  • Beier P
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Abstract

Enamines with in situ formed hydrogen fluoride underwent efficient reaction with trimethyl(1,1,2,2-tetrafluoro-2-(phenylthio)ethyl)silane and trimethyl(1,1,2,2-tetrafluoro-2-(phenylsulfonyl)ethyl)silane. Radical or reductive desulfurization of the addition products provided amines containing the tetrafluoroethyl group.

Author-supplied keywords

  • Enamines
  • Iminium salts
  • Nucleophilic addition
  • Tetrafluoroethyl
  • Tetrafluoroethylene

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Authors

  • Yana Chernykh

  • Bronislav Jurásek

  • Petr Beier

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