Tetrahedral nickel nitrosyl complexes with tripodal [N3] and [Se3] donor ancillary ligands: Structural and computational evidence that a linear nitrosyl is a trivalent ligand

  • Landry V
  • Pang K
  • Quan S
 et al. 
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Abstract

Linear nickel nitrosyl compounds supported by tridentate nitrogen and selenium ligands, namely the tris(3,5-dimethylpyrazolyl)hydroborato and tris(2-seleno-1-mesitylimidazolyl)hydroborato complexes, [TpMe2]NiNO and [TseMes]NiNO, have been synthesized and structurally characterized by X-ray diffraction. Computational studies demonstrate that the linear nitrosyl ligand behaves as a trivalent X3 ligand such that the Ni-N interaction has multiple bond character.

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Authors

  • Victoria K. Landry

  • Keliang Pang

  • Stephanie M. Quan

  • Gerard Parkin

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