Tetrahydrofuran clathrate hydrate formation

  • Conrad H
  • Lehmkühler F
  • Sternemann C
 et al. 
  • 20


    Mendeley users who have this article in their library.
  • 34


    Citations of this article.


We report on the formation of tetrahydrofuran clathrate hydrate studied by x-ray Raman scattering measurements at the oxygen K edge. A comparison of x-ray Raman spectra measured from water-tetrahydrofuran mixtures and tetrahydrofuran hydrate at different temperatures supports stochastic hydrate formation models rather than models assuming hydrate precursors. This is confirmed by molecular dynamics simulations and density functional theory calculations of x-ray Raman spectra. In addition, changes in the spectra of tetrahydrofuran hydrate with temperatures close to the hydrate's dissociation temperature were observed and may be connected to changes in hydrate's local structure due to the formation of hydrogen bonds between guest and water molecules.

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document


  • Heiko Conrad

  • Felix Lehmkühler

  • Christian Sternemann

  • Arto Sakko

  • Dietmar Paschek

  • Laura Simonelli

Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free