Transformation of a 1D to 3D coordination polymer mediated by low temperature lattice solvent loss

  • Chesman A
  • Turner D
  • Deacon G
 et al. 
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Abstract

The desolvation of lattice methanol from between the 1D chains in {[Cu(4,4'-bipyridine)(ccnm)(2)].4MeOH} (ccnm = carbamoylcyanonitrosomethanide) under ambient conditions, a weight loss of 22.4%, results in a solid state conversion to the 3D network [Cu(4,4'-bipyridine)(ccnm)(2)].

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