Zn(tmp) 2 :  A Versatile Base for the Selective Functionalization of C−H Bonds

  • Hlavinka M
  • Hagadorn J
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Abstract

Zn(tmp)2 (tmp = 2,2,6,6-tetramethylpiperidinyl anion) is an effective base for the mild deprotonation of a broad range of substrates. Functionalized organozincs thus prepared are conveniently coupled with aryl bromides using typical Pd-catalyzed coupling methods.
Zn(tmp)2 (tmp = 2,2,6,6-tetramethylpiperidinyl anion) is an effective base for the mild deprotonation of a broad range of substrates. Functionalized organozincs thus prepared are conveniently coupled with aryl bromides using typical Pd-catalyzed coupling methods.

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Authors

  • Mark L. Hlavinka

  • John R. Hagadorn

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