Turning a new leaf: The first structures isolated from Thuiaria breitfussi, the breitfussins, are presented. This structural class consists of indole-oxazole-pyrrole units. Limited quantities prevented crystallization; therefore, the structures were solved using a novel combination of AFM, computer-aided structure elucidation (CASE), and DFT calculations. Visualization by AFM determined all the connection points of the cyclic systems and the other substituents. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
CITATION STYLE
Hanssen, K. O., Schuler, B., Williams, A. J., Demissie, T. B., Hansen, E., Andersen, J. H., … Isaksson, J. (2012). A combined atomic force microscopy and computational approach for the structural elucidation of breitfussin A and B: Highly modified halogenated dipeptides from thuiaria breitfussi. Angewandte Chemie - International Edition, 51(49), 12238–12241. https://doi.org/10.1002/anie.201203960
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