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Effect of hydration on the dielectric properties of C-S-H gel

by Silvina Cerveny, Silvia Arrese-Igor, Jorge S. Dolado, Juan J. Gaitero, Angel Alegra, Juan Colmenero
Journal of Chemical Physics ()
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The behavior of water dynamics confined in hydrated calcium silicate hydrate (C-S-H) gel has been investigated using broadband dielectric spectroscopy (BDS; 10(-2)-10(6) Hz) in the low-temperature range (110-250 K). Different water contents in C-S-H gel were explored (from 6 to 15 wt%) where water remains amorphous for all the studied temperatures. Three relaxation processes were found by BDS (labeled 1 to 3 from the fastest to the slowest), two of them reported here for the first time. We show that a strong change in the dielectric relaxation of C-S-H gel occurs with increasing hydration, especially at a hydration level in which a monolayer of water around the basic units of cement materials is predicted by different structural models. Below this hydration level both processes 2 and 3 have an Arrhenius temperature dependence. However, at higher hydration level, a non-Arrhenius behavior temperature dependence for process 3 over the whole accessible temperature range and, a crossover from low-temperature Arrhenius to high-temperature non-Arrhenius behavior for process 2 are observed. Characteristics of these processes will be discussed in this work.

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Authors on Mendeley

  1. Jon Gaitero
    Researcher (at a non-Academic Institution)
    Bilbao, Spain

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20 Readers on Mendeley
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35% Engineering
30% Materials Science
15% Chemistry
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40% Researcher
30% Student > Ph. D. Student
10% Other
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10% Spain
10% Italy
5% United States

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