Green biosynthesis of anisotropic gold nanoparticles using Ampelopsis grossedentata extract and their shape-controlled by halogen

Abstract

The preparation of size-and shape-controlled metallic nanoparticles using biological methodologies is a noticeably stimulating research field due to their unique physicochemical properties. In this paper, biosynthesis of anisotropic AuNPs using Ampelopsis grossedentata extract and the effects of halide ions on the formation of AuNPs has been demonstrated. The sizes and morphologies of AuNPs were characterized by UV-vis-NIR spectrophotometer and Transmission Electron Microscopy (TEM). It showed that the shape, size and optical properties of AuNPs can be fine-tuned by varying the dosage of the Ampelopsis grossedentata extract. The presence of halogen ions has significantly influence on the morphology of AuNPs during the synthesis process. Both of Br-and Cl-could produce nanoplates, whereas I-distorted the triangle nanoparticles to induce the formation of aggregated spherical ones.