Air-sea flux of bromoform: Controls, rates, and implications

Abstract

Bromoform (CHBr3) is the largest single source of atmospheric organic bromine and therefore of importance as a source of reactive halogens to the troposphere and lower stratosphere. The sea-to-air flux, originating with macroalgal and planktonic sources, is the main source for atmospheric bromoform. We review bromoform's contribution to atmospheric chemistry, its atmospheric and oceanic distributions and its oceanic sources and sinks. We have reassessed oceanic emissions, based on published aqueous and airborne concentration data, global climatological parameters, and information concerning coastal and biogenic sources. The goals are to attempt an estimate of the global source strength and partly to identify key regions that require further investigation. The sea-to-air flux is spatially and temporally variable with tropical, subtropical and shelf waters identified as potentially important source regions. We obtain an annual global flux of bromoform of ∼ 10 Gmol Br yr-1 (3-22 Gmol Br yr-1). This estimate is associated with significant uncertainty, arising from data precision and coverage, choice of air-sea exchange parameterizations and model assumptions. Anthropogenic sources of ∼0.3 (to 1.1) Gmol Br yr-1 (as CHBr3) can be locally significant, but are globally negligible. Our estimate of the global oceanic source is three to four times higher than recent estimates based on the modeling of atmospheric sinks. The reasons for this discrepancy could lie with the limited regional and temporal data available and the broad assumptions that underlie our flux calculations. Alternatively, atmospheric sink calculations, often made on the basis of background CHBr3 levels, may neglect the influence of strong but highly localized sources (e.g., from some coastal and shelf regions). The strongly variable and poorly characterized source of CHBr3, together with its short atmospheric lifetime, complicates model-based estimation of the distribution of reactive Br resulting from its atmospheric degradation. An integrated program of marine and atmospheric observations, atmospheric modeling and mechanistic studies of oceanic bromoform production is required to better constrain present and future Br delivery to the atmosphere.