Exhaust after treatment for lean burn and diesel engine is a complex catalytic system that consists of a number of catalytic units. Pt/Al2O3is often used as a model Diesel Oxidation Catalyst (DOC) that plays an important role to facilitate oxidation of NO to NO2. In the present study, we proposed a detailed kinetic model of NO oxidation as well as low temperature C3H6 inhibition to simulate temperatureprogrammed reaction (TPR) data for NO oxidation over Pt/Al2O3. A steady-state microkinetic model based on Langmuir-Hinshelwood mechanism for NO oxidation was proposed. In addition, low temperature C3H6inhibition was proposed as a result of site blocking as well as surface nitrite consumption. The model can explain the experimental data well over the studied temperature range.
CITATION STYLE
Azis, M. M., & Creaser, D. (2016). Kinetic modeling of C3H6 inhibition on NO Oxidation over Pt Catalyst. In Bulletin of Chemical Reaction Engineering and Catalysis (Vol. 11, pp. 27–33). Diponegoro University. https://doi.org/10.9767/bcrec.11.1.412.27-33
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