Control of Properties through Hydrogen Bonding Interactions in Conjugated Polymers

Abstract

Molecular design is crucial for endowing conjugated polymers (CPs) with unique properties and enhanced electronic performance. Introducing Hydrogen-bonding (H-bonding) into CPs has been a broadly exploited, yet still emerging strategy capable of tuning a range of properties encompassing solubility, crystallinity, electronic properties, solid-state morphology, and stability, as well as mechanical properties and self-healing properties. Different H-bonding groups can be utilized to tailor CPs properties based on the applications of interest. This review provides an overview of classes of H-bonding CPs (assorted by the different H-bond functional groups), the synthetic methods to introduce the corresponding H-bond functional groups and the impact of H-bonding in CPs on corresponding electronic and materials properties. Recent advances in addressing the trade-off between electronic performance and mechanical durability are also highlighted. Furthermore, insights into future directions and prospects for H-bonded CPs are discussed.