Hetero Diels-Alder Adduct Formation between Nitrosobenzene and Tetra-methyl Purpurogallin and its retro-Diels-Alder Reaction

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Abstract

An efficient synthesis of a Diels-Alder adduct between purpurogallin tetramethyl ether (TMPG) and nitrosobenzene (NOB) is reported. The thermal decomposition kinetics of the adduct, which follows a retro-Diels-Alder mechanism, was studied using 1H-NMR spectroscopy.

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Gamenara, D., Días, E., Tancredi, N., Heinzen, H., Moyna, P., & Forbes, E. J. (2001). Hetero Diels-Alder Adduct Formation between Nitrosobenzene and Tetra-methyl Purpurogallin and its retro-Diels-Alder Reaction. Journal of the Brazilian Chemical Society, 12(4), 489–492. https://doi.org/10.1590/S0103-50532001000400008

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