Synthesis, characterization and physicochemical properties of oleic acid ether derivatives as biolubricant basestocks

Abstract

Petroleum is a finite source as well as causing several environmental problems. Therefore petroleum needs to be replaced by alternative and sustainable sources. Plant oils and oleochemicals derived from them represent such alternative sources; the use of oleochemicals as biobased lubricants is of significant interest. This article presents a series of chemical modification on oleic acid to yield synthetic biolubricant basestocks. Measuring of density, volatility, cloud point (CP), pour point (PP), fl ash point (FP), viscosity index (VI), onset temperature (OT) and signal maximum temperature (SMT) was carried out for each compound. Furthermore, the friction and wear properties were measured using high-frequency reciprocating rig (HFRR). The results showed that octadecyl 9-octadecyloxy-10-hydroxyoctadecanoate exhibited the most favorable low-temperature performance (CP -26°C, PP -28°C) and the lowest ball wear scan diameter (42 μm) while propyl 9-propyloxy-10-hydroxyoctadecanoate exhibited the higher oxidation stability (OT 156°C). © 2011 by Japan Oil Chemists' Society.