Rotational and Vibrational Excitation of Molecules

Abstract

Techniques for the determination of rotational and vibrational excitation cross sections of molecules by low-energy electrons are reviewed. The results of experiment are then compared with theory. High-energy resolution electron beam techniques are most useful for the measurement of the details of resonance-type, vibrational excitation cross sections. Cross section determinations from analyses of electron transport coefficients are most successful at energies near the threshold of vibrational excitation and for rotational excitation. High-frequency energy relaxation studies provide data on rotational excitation. A comparison of presently available experimental and theoretical results shows that some of the excitation processes, e.g., rotational excitation of N2 and CO and vibrational excitation of CO near threshold, are accurately described by the longest-range forces and Born approximation. In other cases, e.g., vibrational excitation of N2 and CO near 2 eV, the excitation is best described in terms of an electron resonance with the molecular potential. © 1968 The American Physical Society.