Abstract
(Chemical Equation Presented) At the palladium: Dimeric palladium bromide complexes bearing monodentate N-heterocyclic carbene ligands have been identified as efficient catalysts for the chemoselective racemization of axially chiral allenyl alcohols. In combination with porcine pancreatic lipase as biocatalyst, a dynamic kinetic resolution has been developed, giving access to optically active alienes in good yield and high enantiomeric purity (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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Bäckvall, J. E., Deska, J., & Del Pozo Ochoa, C. (2010). Chemoenzymatic dynamic kinetic resolution of axially chiral alienes. Chemistry - A European Journal, 16(15), 4447–4451. https://doi.org/10.1002/chem.201000301
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