Global patterns of radiocarbon depletion in subsoil linked to rock-derived organic carbon

Abstract

Organic matter stored in sedimentary rocks is one of the largest stocks of carbon at Earth’s surface. The fate of this rock organic carbon (OCpetro) during weathering in soils influences the geological carbon cycle, and impacts soil radiocarbon content that is used to quantify soil carbon turnover. Here, we assess the potential contribution of OCpetro to soils, using a mixing model generated by a global dataset of soil radiocarbon measurements (14C). Soils developed on sedimentary rocks (rather than on igneous substrate) have a paired OC content and 14C values consistent with OCpetro input, giving rise to apparent increase in soil residence time. We call for renewed assessment of OCpetro input to soils, in terms of its impact on soil radiocarbon inventories, and its potential to release carbon dioxide.