New O and Fe stable isotope ratios are reported for magnetite samples from high-grade massive magnetite of the Mesoproterozoic Pea Ridge and Pilot Knob magnetite-apatite ore deposits and these results are compared with data for other iron oxide-apatite deposits to shed light on the origin of the southeast Missouri deposits. The d18O values of magnetite from Pea Ridge (n = 12) and Pilot Knob (n = 3) range from 1.0 to 7.0 and 3.3 to 6.7%, respectively. The d56Fe values of magnetite from Pea Ridge (n = 10) and Pilot Knob (n = 6) are 0.03 to 0.35 and 0.06 to 0.27%, respectively. These d18O and the d56Fe values suggest that magnetite crystallized from a silicate melt (typical igneous δ56Fe ranges 0.06-0.49%) and grew in equilibrium with a magmatic-hydrothermal aqueous fluid. We propose that the δ18O and δ56Fe data for the Pea Ridge and Pilot Knob magnetite-apatite deposits are consistent with the flotation model recently proposed by Knipping et al. (2015a), which invokes flotation of a magmatic magnetite-fluid suspension and offers a plausible explanation for the igneous (i.e., up to 15.9 wt % TiO2 in magnetite) and hydrothermal features of the deposits.
CITATION STYLE
Childress, T. M., Simon, A. C., Day, W. C., Lundstrom, C. C., & Bindeman, I. N. (2016). Iron and oxygen isotope signatures of the pea ridge and pilot knob magnetite-apatite deposits, Southeast Missouri, USA. Economic Geology, 111(8), 2033–2044. https://doi.org/10.2113/econgeo.111.8.2033
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