Abstract
Gas up: A cyclometalated iridium complex is found to catalyze the dehydrogenation of various benzofused N-heterocycles, thus releasing H 2. Driven by as low as 0.1 mol % catalyst, the reaction affords quinolines, indoles, quinoxalines, isoquinolines, and β-carbolines in high yields. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Wu, J., Talwar, D., Johnston, S., Yan, M., & Xiao, J. (2013). Acceptorless dehydrogenation of nitrogen heterocycles with a versatile iridium catalyst. Angewandte Chemie - International Edition, 52(27), 6983–6987. https://doi.org/10.1002/anie.201300292
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