Abstract
Highly selective: The reduction of α-methyl-substituted nitroalkenes succeeds in a highly enantioselective fashion with an ene reductase from Gluconobacter oxydans. Under optimized reaction conditions the desired nitroalkanes are formed with enantiomeric excesses of up to 95% in these biotransformations. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Burda, E., Reß, T., Winkler, T., Giese, C., Kostrov, X., Huber, T., … Gröger, H. (2013). Highly enantioselective reduction of α-methylated nitroalkenes. Angewandte Chemie - International Edition, 52(35), 9323–9326. https://doi.org/10.1002/anie.201301814
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