Mechanical properties and permeability of red mud-blast furnace slag-based geopolymer concrete

Abstract

Red mud, a by-product of alumina production, has a great impact on the environment due to its high alkalinity. In this paper, two-part geopolymer mortar was synthesized by combining red mud and blast furnace slag (BFS) to obtain optimized compressive strength and flexural strength for construction materials. Geopolymer concrete was prepared with the cementitious material in the concrete replaced by geopolymer mortar. Mechanical properties, permeability and microscopic properties of geopolymer concrete were measured. The results showed that the compressive strength grade of concrete prepared with geopolymer concrete can reach 54.43 MPa indicating that the geopolymer concrete can be used as materials for load-bearing members in structures. Due to lower total porosity and better pore structure, the permeability resistance of geopolymer concrete was significantly better than ordinary concrete. Microscopic analysis indicated that a large amount of aluminosilicate reaction products was generated in a geopolymer by the reaction of OH− with the aluminosilicate components in red mud and BFS in a strongly alkaline environment. The surface [SiO4]4− and [AlO4]4− tetrahedrons form chemical bonds through dehydroxylation, which is the direct reason for their high strength and determines their excellent physical and chemical properties.