Atomic structure and morphology of fumed silica

Abstract

The comparative analysis of atomic structure and morphology of fumed silica nanoparticles prepared under different synthesis conditions has been carried out using TEM, FTIR, quantum chemistry, and low-temperature nitrogen adsorption methods. It has been determined that the structure of amorphous silica nanoparticles is formed by branched chain-like clusters of 0.6 - 2.4 nm in size that correspond to proto-particles or nuclei of nanoparticles. A linear part of the smallest clusters is consisted of two tetrahedra SiO4with common oxygen atom and oppositely directed vertices. The inter-tetrahedral average angle Si - O - Si is ca. 180°. It has been shown that the textural porosity of fumed silica powder depends on the initial degree of aggregation of nanoparticles. The average mesopores (1 nm < R < 25 nm) volume is in the rage of 0.26 - 0.60 cm3·g-1for materials pretreated at different temperatures. It has been found out that the mean pores radius decreases from 34 nm to 10 nm with decreasing average size of silica nanoparticles. The micropores (R < 1 nm) contribution to the total pore volume is small for all materials (0.003 - 0.029 cm3·g-1).