Densification Behaviour and Mechanical Properties of Aluminium Oxide and Cerium Oxide-Doped Yttria Tetragonal Zirconia Polycrystal Ceramics Using Two-Step Sintering

Abstract

The densification behaviour, mechanical properties, and microstructure of high-purity Al 2 O 3 and CeO 2 -doped Y-TZP with different weight percentage varied from 0.3 to 1 wt% were investigated. The samples were pressed uniaxially at 200 MPa into rectangular bars and discs and pressureless-sintered at temperature ranging between 1250°C and 1450°C for 2 h while the microstructure was characterized with a scanning electron microscope (SEM). Two-step sintering process works well for temperature higher than 1400°C and it created most tetragonal phase arrangement for stable structure to delay ageing through phase transformation. The mechanical properties in terms of bulk density, Young’s modulus, Vickers hardness, and fracture toughness were also measured. The results indicate that the addition of dopants accelerated the densification parameters and reinforced and toughened the obtained bodies. The maximum values for the mechanical properties of the Al 2 O 3 and CeO 2 -doped Y-TZP ceramics were 6.01, 220 GPa, 13.8 GPa, and 7 MPa for density, Young’s modulus, Vickers hardness, and fracture toughness, respectively, which are higher than those of the doped samples.