Synthesis, Characterization and Catalytic Activity of Binary PtMn/C Alloy Catalysts towards Ethanol Oxidation

  • Ammam M
  • Prest L
  • Pauric A
  • et al.
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Abstract

Binary PtMn/C alloy catalysts with various atomic ratios (60-90 atomic Mn) were synthesized and tested for the activity toward ethanol oxidation. The synthesized catalysts were characterized by energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). XRD studies indicate that a Pt-Mn alloy has formed in all cases. PtMn(19:81)/C and PtMn(10:90)/C exhibited the highest activity toward ethanol oxidation compared to PtMn(39:61)/C and PtC. XPS analysis indicates that highest activity occurs for alloys with similar surface and bulk Mn contents. © 2011 The Electrochemical Society.

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Ammam, M., Prest, L. E., Pauric, A. D., & Easton, E. B. (2011). Synthesis, Characterization and Catalytic Activity of Binary PtMn/C Alloy Catalysts towards Ethanol Oxidation. Journal of The Electrochemical Society, 159(2), B195–B200. https://doi.org/10.1149/2.095202jes

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