One-step synthesis of 1,6-hexanediamine modified magnetic chitosan microspheres for fast and efficient removal of toxic hexavalent chromium

Abstract

Here, we reported a novel one-step hydrothermal route for the facile synthesis of 1,6-hexanediamine functionalized magnetic chitosan microspheres (AF-MCTS), which were characterized by TEM, FT-IR and XPS to look into its morphology, surface functional groups, and adsorption mechanism of Cr(VI) from the aqueous solution. Cr(VI) adsorption on AF-MCTS as a function of contact time, Cr(VI) concentration, pH, and ionic strength was investigated. The adsorption process follows the Langmuir isotherm model and pseudo-second-order kinetic model. The AF-MCTS exhibited high performance for Cr(VI) removal with very fast adsorption rate (reaching equilibrium within 5 min) and high adsorption capacity (208.33 mg/g), which was 1.1 to 12 times that of other chitosan-based adsorbents. Cr(VI) adsorption onto AF-MCTS was an endothermic and spontaneous process. The recovery and reuse of AF-MCTS was demonstrated 11 times without obvious decrease in adsorption capacity. Mechanism study suggested that –OH rather than –NH2 groups in AF-MCTS were the electron donors for reducing Cr(VI) to Cr3+. Consumption or addition of H+ could trigger the reversible supramolecular coordination between Cr3+ and chitosan. Given the easy preparation, low cost, and remarkable performance, AF-MCTS composite is expected to show promising potential for the practical application in removing toxic Cr(VI) from aqueous media.