Reduction Behavior of Dolomite-Fluxed Magnetite: Coke Composite Pellets at 1573 K (1300 °C)

Abstract

High-temperature behavior of magnetite—coke composite pellet fluxed with dolomite was investigated by customized thermogravimetric analyzer (TGA) at 1573 K (1300 °C). The overall reaction was influenced by C/O ratio and dolomite content. The reduction was accelerated by increased amount of dolomite, while the samples with higher C/O ratio showed the improved reduction degree. X-ray diffraction (XRD) pattern of reduced pellet showed the phase changes of the iron oxides. Noticeable iron peaks were observed when the sample reached the final stage of reduction. CO and CO2 gases released from the reaction were measured by Infrared (IR) gas analyzer. Relation between enhanced reducibility of pellets and larger CO gas evolution from the Boudouard reaction was confirmed from the analysis. Compressive strengths were studied for the practical assessment of reduced pellets. Samples with low-reduction degree showed better physical property. Excessive amount of dolomite also deteriorated the integrity of pellets.