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Highly controlled ring-opening of siloxydifluorocyclopropanes: A versatile route to cyclic fluoroketones

Synlett (2015) 26(1) 63-66
DOI: 10.1055/s-0034-1379599
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Abstract

A convenient access to cyclic fluoroketones that involves base-promoted ring-opening of siloxydifluorocyclopropanes is presented. Selective formation of gem-difluorinated cycloalkanones and monofluorinated enones has been achieved.

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Kageshima, Y., Suzuki, C., Oshiro, K., & Amii, H. (2015). Highly controlled ring-opening of siloxydifluorocyclopropanes: A versatile route to cyclic fluoroketones. Synlett, 26(1), 63–66. https://doi.org/10.1055/s-0034-1379599

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