Synthesis of CuO for microwave-assisted pyrolysis of biomass

Abstract

In this study, CuO was synthesized as a microwave absorber in the pyrolysis of a biomass model (sugarcane bagasse). CuO was synthesized for 5 min of irradiation using the following techniques: microwave (MW), ultrasound (US), combined mode (MW-US), and conduction heating (CH) as a reference material. The use of these treatments promotes changes in the morphology, as MW and US generate leaves and monolithic faceted morphologies, respectively. Changes were also generated in some textural characteristics such as crystal size, surface area, and volume-pore size. They were produced as a consequence of changes in the conditions during the crystallization stage produced by the different irradiation types. The microwave-assisted pyrolysis was performed aiming for the maximum liquid fraction (bio-oil) in the products. The reaction time, the size of the biomass, and the CuO synthesis method were also analyzed. The following particle size (ps) intervals were studied: ps < 0.5 mm, 0.5 mm < ps < 1.7 mm, 1.7 mm < ps < 3.5 mm. The best conditions at 1160Watts in the microwave were: 4 min of reaction, particle size lower than 0.5 mm, and CuO synthesized by US. The use of CuO in the pyrolysis almost triples the amount of the obtained liquid fraction, when compared with the pyrolysis without the use of a microwave absorbent. The CuO was reduced to Cu2O and Cu after the pyrolysis. In this work, a reduction in the reaction times from hours to minutes was achieved during the synthesis of CuO and the pyrolysis biomass. The liquid fraction (bio-oil) can be raw material to obtain value-added chemical products or biofuels.