Determination of lead in croatian wines by graphite furnace atomic absorption spectrometry

Abstract

A method has been developed for direct determination of lead in wine by graphite furnace atomic absorption spectrometry (GFAAS) with Zeeman-effect background correction. The thermal behaviour of Pb during pyrolysis and atomisation stages was investigated without matrix modifi er and in the presence of Pd(NO3)2, Pd(NO3)2 + Mg(NO 3)2 x 6H2O, and NH4H 2PO4 + Mg(NO3)2 x 6H2O as matrix modifi ers. A simple 1:1 dilution of wine samples with Pd(NO 3)2 as a matrix modifi er proved optimal for accurate determination of Pb in wine. Mean recoveries were 106 % for red and 114 % for white wine, and the detection limit was 3 μg L-1. Within-run precision of measurements for red and white wine was 2.1 % and 1.8 %, respectively. The proposed method was applied for analysis of 23 Croatian wines. Median Pb concentrations were 33 μg L-1, range (16 to 49) μg L-1 in commercially available wines and 46 μg L-1, range (14 to 559) μg L-1 in home-made wines. There were no statistically signifi cant differences (P<0.05) in Pb concentration between commercial and home-made wines or between red and white wines.