Facile synthesis of aminated indole-based porous organic polymer for highly selective capture of CO2 by the coefficient effect of π-π-stacking and hydrogen bonding

Abstract

A new aromatic aminated indole-based porous organic polymer, PIN-NH2, has been successfully constructed, and it was demonstrated that the coefficient effect endows this porous material with outstanding CO2 absorption capacity (27.7 wt%, 1.0 bar, 273 K) and high CO2/N2 (137 at 273 K and 1 bar) and CO2/CH4 (34 at 273 K and 1 bar) selectivity.